Process of making roofing material

ABSTRACT

A laminated roofing material includes an aluminum foil top sheet laminated to a polyethylene film by an ionomer resin. After the sheets are bonded together they are cooled to set the resin and a bitumen coating is applied to the exposed polyethylene sheet and covered with a release paper.

FIELD OF THE INVENTION

This invention relates to a process for making laminated roofing materials, the unique apparatus for carrying out the process and the resulting roofing product.

BACKGROUND OF THE INVENTION

A roofing product needs a means for attaching the roofing to the surface to be covered, a strengthening layer to maintain the integrity of the roofing layer and an upper surface to be in contact with the environment to minimize the exposure of the layers below.

It is well recognized that the ultraviolet rays from the sun are most destructive to exposed asphalt surfaces.

Applications of coal-tar and asphalt layers as part of roofing must be shielded from the sunlight. The ultraviolet light tend to polymerize the hydrocarbon molecules and harden the surface which results in cracking of the asphalt and leaks in the roof. Conventional ways of shielding the asphalt layer is with crushed rock or gravel, flakes of aluminum, aluminum paint, etc.

Examples of two attempts to solve the roofing problem are illustrated in U.S. Pat. Nos. (Jackson) 3,770,559 and (Hurst) 3,900,102.

The Jackson patent discloses a plurality of layers having an aluminum foil sheet bonded to a bituminous adhesive re-enforced with a nylon-fabric.

The Hurst patent discloses a surface coating material for masonry surfaces which includes a fabric impregnated with a bitumen mixture.

SUMMARY OF THE INVENTION

A roofing material according to the instant invention includes an upper layer of aluminum foil to reflect infrared and ultraviolet rays impinging on the roofing from the sun. The aluminum may be relatively thin and very flexible because it is not intended to serve as a strengthening element. The infrared rays reflected reduce the heat transmitted to the roofing surface.

The aluminum foil is bonded to a high density polyethylene film by an ionomer resin. The polyethylene film is to provide structural integrity of the roofing sheet and while it has a good elasticity and strength in tension, it is sufficiently resilient to hold or pull the roofing back into its original shape even though it may be temporarily distorted by tension forces.

The under side of the polyethylene film includes a coating of bitumen. The bitumen coating serves as an adhesive to bond the upper layer of the roofing to the roof itself. Additionally, the bitumen has the property of being self-sealing at 60° F. and above and will tend to seal punctures and breaks in the polyethylene film should any occur, thereby maintaining the integrity of the waterproofing to be provided by the roofing material. The bitumen is a mixture of asphalt, styrene-butadiene radial block copolymer, aromatic processing oil, hydrocarbon tackifying resin, antioxidant, and finely ground silica sand. It is mixed and blended in unique proportions and under unique physical conditions to achieve the desired puncture-proofing flowability characteristics.

The roofing is manufactured to be wound into a spiral roll and cut to appropriate sizes. As a result, a release paper is applied to the exposed surface of the bitumen coating to prevent the bitumen from adhering to whatever it comes into contact with before the roofing sheet is applied to the appropriate surface.

The roofing may be wound in a spiral roll with the release paper being in direct contact with the aluminum foil upper sheet and a conventional roll would be thirty-six inches wide and thirty-three and one-half feet long. In addition this roofing product may be used as a patching material to patch leaks in conventional roofs, walls, gutters, or the like when cut to narrow widths.

In applying the roofing, it may be necessary to clean the roofing surface before the roofing material is applied. For proper adhesion the roofing of this invention must be applied to a clean dry surface which is relatively flat and is free from loose debris, oils, greases, or the like. In some instances it may be appropriate to use a butyl caulking to enhance the edge bonding of the roofing material or to seal around the edge of said roofing material.

Objects of the invention not clear from the above will be fully understood from a review of the attached drawings and the description of the preferred embodiments which follow.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a perspective view of a roll of roofing according to this invention showing the various layers, not in proportion;

FIG. 2 is a perspective view illustrating a way the roofing material would be applied to a roof;

FIG. 3 is a perspective view showing a piece of the roofing material used to patch a hole in a gutter;

FIG. 4 is a sectional view taken along line 4--4 of FIG. 1 showing the rough proportions in thickness of the various layers of the roofing material;

FIG. 5 is a diagrammatic view showing the first part of the manufacturing process where the aluminum foil is bonded to the polyethylene sheet;

FIG. 6 is a diagrammatic view of the mixing system for the bitumen;

FIG. 7 is a diagrammatic view of the coating of the polyethylene sheet with bitumen and the simultaneous application of the release paper; and

FIG. 8 is a perspective view of the way the bitumen is applied to the polyethylene layer.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Looking to FIGS. 1-4, a roll of roofing material 10 is provided having five layers which will be described subsequently. In particular FIG. 2 illustrates the application of the roofing material to a roof 12. FIG. 3 shows the roof 12 having attached thereto a gutter 14 and a patch 16 of the roofing material which is bonded into the gutter to patch a leak.

FIG. 4 illustrates the roofing material in section to give a rough idea of the proportional thicknesses of the layers of product involved in this invention. The uppermost surface is the one to be exposed to sunlight and the environment in general and it is an aluminum foil sheet 18 having a desired thickness of about 0.0007 inches. It is adhesively bonded to a polyethylene sheet 20 (having a thickness of about 0.004 inches) by an ionomer resin adhesive 22. The preferred resin adhesive is sold by the DuPont Company under the trademark SURLYN but other equivalent resins would be within the concept of the invention. A suitable cross-link high-density polyethylene film is purchased from Van Leer Plastics Company under the trademark VALERON 4020.

A coating of bitumen 24 is bonded to the surface of the polyethylene sheet 20 and is intended to serve as an agent to seal around punctures or cracks which may occur in polyethylene layer 20 and to bond the roofing laminate to the surface to be covered. To prevent the bitumen coating 24 from adhering to the aluminum foil when the roofing laminate is wound into a spiral roll, a release paper 26 is applied over the exposed bitumen surface. The preferred release paper is a densified bleached Kraft paper coated with a silicon compound for release. A suitable release paper is available from Mead Release Products, James River Corporation and any number of other sources.

Describing now the process of making the product and the apparatus for performing the manufacturing process as shown in FIG. 5, a roll of polyethylene film 28 is unwound and passed through a corona process or treatment station 30 which serves to make the surface of the polyethylene film more receptive to the adhesive to be applied between it and the aluminum foil. The polyethylene film continues along its route to pass between a pair of rollers 32, 34 which squeezes the polyethylene film against a correspondently sized sheet of aluminum foil 36 being feed from a supply roll 38. As the foil and film are being pressed together by rolls 32 and 34 an adhesive 40 is being extruded from a supply nozzle 42 to bond the aluminum and polyethylene sheets together. The roll 34 is maintained at a temperature of about 35° to 40° F. and serves as chill roll to set the adhesive and form the initial laminate which may be collected on a roll 44 or the laminate could be supplied directly to the next laminating process shown in FIG. 7.

The roll of laminate 44 is an intermediate product and it will be passed between a second pair of rollers 46, 48 which are maintained at about 55° F. to chill the hot bitumen coating 24 as it is applied to the polyethylene sheet 20.

The laminate from roll 44 passes as a sheet 50 over roll 46 simultaneously with a sheet of release paper 26 from a supply roll 52, the release paper passing over roll 48. The coating 24 of bitumen is applied in a thickness controlled by the spacing between rolls 46 and 48.

After the preliminary chilling of the bitumen coating 24 by chill rolls 46, 48, the five layer laminate is passed around a roll 54 which serves to press the release paper 26 more tightly against the bitumen layer 24 and further enhance the bonding of the bitumen layer to the polyethylene sheet. Thereafter, the five layer laminate passes over a series of cooling or chilling rolls 56 to bring the laminate down to near atmospheric temperature.

Note the right-hand side of FIG. 7, the marker 58. There are in fact two markers, one on each side of the roofing to mark the desired overlap of the roofing rolls. A mark is in fact made on each side of the sheet, preferably three inches from the edge, to show the roofing installation workman the proper location of the subsequently supplied roofing sheet. A mark is made on each edge of the sheet because it is not certain which edge will be the upside of the roof during the assembly process.

During the initial research stages of the invention, consultation was had with an expert in the field of roof coating asphalts and an initial formulation was suggested. Various changes were made subsequently during the experimentation period and the following shows the original recommendation along with the current desired proportional ingredients:

    ______________________________________                                         Ingredient          Original Current                                           ______________________________________                                         Bitumen             51 parts 63                                                Solprene or Finaprene 411                                                                           5       4                                                 Solprene or Finaprene 1205                                                                         11       9                                                 Filler              15       12                                                Stalite              0.25    0.4                                               Sundex 790          12       7                                                 Escorez 2101         5       5                                                 ______________________________________                                    

The bitumen is a straight-run (unblown) asphalt with a softening point of about 100°-120° F. and a penetration of 90-140 dmm (this is a standard designation of a grade of bitumen). SOLPRENE and FINAPRENE are styrene-butadiene linear block co-polymers, a thermal plastic elastomer. SOLPRENE is a trademark of Phillips Petroleum and FINAPRENE is a trademark of Fina Oil and Chemical Company. The products are functional equivalents.

The filler is a ground silica sand of about 325 mesh grade.

SUNDEX is a trademark of Sun Oil Company used in relation to an aromatic processing oil.

ESCOREZ is a trademark of Exxon Chemical Company and is used in relation to a hydrocarbon tackifying resin.

STALITE is a trademark of Vanderbilt Company and is used in association with an antioxidant which is incorporated into the system to minimize cross-linking of the molecules of the asphalt.

Looking now to FIG. 6 batches of the bitumen are initiated in a first mixing vat 60 where the bitumen is deposited at about 360° F. and the styrene-butadiene, antioxidant, aromatic processing oil, and hydrocarbon tackifying resin are added. The ingredients are mixed 62 in the vat and are circulated through a mixer/homogenizer 64 in recirculating pipes 66 and 68 for over an hour and preferably about seventy minutes. The homogenizer 64 is a vigorous acting pump and the bitumen mixture is rather viscous and as a result of the mixing and recirculation activities the temperature of the mixture will rise to about 390°-420° F. during the seventy minute homogenizing process.

After the bitumen mixture is satisfactorily homogenized it is discharged through pump 64 and pipe 66 by closing valve 70 and opening valve 72 such that the bitumen passes through piping 74 into a second or holding vat or tank 76.

In tank 76 the ground silica sand is deposited and mixed by a mixer 78 to a generally homogeneous consistency. When the holding tank 76 has the mixture adequately mixed it can be discharged by opening valve 80 and the bitumen will flow through pipe 82 to a space between and above rollers 46 and 48, see FIG. 7.

Looking to FIG. 8, the bitumen mixture will be deposited in the space between rollers 46 and 48 and will form a puddle 84 between a pair of laterally spaced guides 86, 88 which will prevent lateral flow of the bitumen during the manufacturing process. It will be observed that the guides keep the bitumen from any direct contact with the rolls 46 and 48, thus the bitumen is confined between the release paper 26 and the laminate 50.

In the mixing of the sand and bitumen in vat 76 the proportion of sand will be one part sand and from six to seven and one-half parts of the bitumen mixture from vat 60. Preferably the proportion of bitumen from vat 60 will be closer to the seven and one-half parts ratio because of the better flow characteristics at 60° F. and above and thereby the puncturing sealing characteristics of the bitumen is enhanced.

Because of the viscosity of the bitumen, the mixture in vat 76 is maintained at about 325° F. during its mixing and holding period. Thereby, when the mixture is discharged from outlet pipe 82 between guides 86 and 88 the bitumen will be at 325° F. or less because of the heat loss in passing through the discharge system and into the puddle 84 above the rolls 46 and 48.

Having thus described the invention in its preferred embodiment it will be clear that changes may be made in certain aspects of the procedural, proportional and apparatus parts of this invention without departing from the spirit of the invention. Accordingly, it is not intended that the invention be limited by the words used to describe the invention nor the drawings showing the same. Rather it is intended that the invention be limited only by the scope of the appended claims. 

We claim:
 1. A process for making a laminated roofing material comprising, in sequence:extruding an adhesive from a nozzle, depositing said adhesive between an aluminum foil sheet and a sheet of polyethylene film, pressing the two sheets together, said adhesive being an ionomer resin and being maintained at a temperature to flow from said extruding nozzle, cooling the adhesive and sheets to set said adhesive to form a laminated sheet, coating the polyethylene side of the laminated sheet with a hot liquid bitumen mixture and covering said bitumen coating with a release paper, cooling the bitumen to secure it to the polyethylene, and rolling said coated sheet in a spiral roll with the release paper in contact with the aluminum foil.
 2. The process of claim 1 including making the polyethylene more receptive to said adhesive by the further step of providing a corona treatment to the surface of the polyethylene film prior to the time the adhesive is deposited between the polyethylene film and the aluminum foil.
 3. The process of claim 2 including applying the bitumen to the polyethylene at a temperature below about 325° F.
 4. The process of claim 3 wherein the bitumen mixture is comprised of:(a) a straight-run, unblown, asphalt with a softening point of 100°-120° F. and penetration of 90-140 dmm; (b) a styrene-butadiene radial block polymer; (c) an antioxidant to minimize cross-linking of asphalt molecules; (d) an aromatic processing oil to enhance bonding between styrene-butadiene and the asphalt; and (e) a hydrocarbon tackifying resin. blending the mixture at a temperature of 390°-420° F. for over one hour to insure a uniform mixture and delivering said blended mixture to a holding tank where it is maintained at about 325° F. until it is applied as a coating to the polyethylene sheet.
 5. The process of claim 4 including adding sand to the blended mixture in the holding tank,mixing the sand and blended mixture to a uniform mixture before discharging said uniform mixture as a coating.
 6. The process of claim 5 including mixing said sand with the blended mixture in the proportions of about 6-7.5 parts of the blended mixture to one part silica sand of about 325 mesh grade.
 7. The process of claim 1 wherein the bitumen mixture is comprised of:(a) a straight-run, unblown, asphalt with a softening point of 100°-120° F. and penetration of 90-140 dmm; (b) a styrene-butadiene radial block polymer; (c) an antioxidant to minimize cross-linking of asphalt molecules; (d) an aromatic processing oil to enhance bonding between styrene-butadiene and the asphalt; and (e) a hydrocarbon tackifying resin. blending the mixture at a temperature of 390°-420° F. for over one hour to insure a uniform mixture and delivering said blended mixture to a holding tank where it is maintained at about 325° F. until it is applied as a coating to the polyethylene sheet.
 8. The process of claim 7 including adding sand to the blended mixture in the holding tank,mixing the sand and blended mixture to a uniform mixture before discharging said uniform mixture as a coating.
 9. The process of claim 8 including mixing said sand with the blended mixture in the proportions of about 6-7.5 parts of the blended mixture to one part silica sand of about 325 mesh grade.
 10. The process of claim 1 including applying the bitumen to the polyethylene at a temperature below about 25° F. 